Rechargeable batteries (secondary batteries) are electrochemical energy storage devices that can be repeatedly charged and discharged through reversible chemical reactions. Unlike primary batteries, they form the backbone of modern energy storage systems, enabling portable electronics, electric vehicles (EVs), and renewable energy integration. Their ability to reduce long-term costs and environmental impact makes them critical in sustainable technology development.
| Type | Functional Characteristics | Application Examples |
|---|---|---|
| Lithium-ion (Li-ion) | High energy density (100-265 Wh/kg), low self-discharge, long cycle life (500-2000 cycles) | Smartphones, EVs, laptops |
| Nickel-Metal Hydride (NiMH) | Moderate energy density (60-120 Wh/kg), environmental friendliness, memory effect resistance | Hybrid vehicles, digital cameras |
| Lead-Acid | Low cost, high surge current capability, heavy weight | Automotive starters, backup power systems |
| Lithium Iron Phosphate (LiFePO4) | Exceptional thermal stability, long lifespan (2000+ cycles), lower energy density | Electric buses, solar storage, marine applications |
Typical rechargeable battery cells consist of:
Cell designs include cylindrical (18650 format), prismatic, and pouch configurations with integrated protection circuits.
| Parameter | Description | Importance |
|---|---|---|
| Energy Density | Wh/kg or Wh/L | Determines runtime and weight |
| Charge Cycle Life | Number of full discharge/charge cycles | Dictates longevity and cost-effectiveness |
| Internal Resistance | Measured in milliohms | Affects power output and efficiency |
| Self-Discharge Rate | Monthly capacity loss percentage | Storage performance indicator |
| Charging Efficiency | Percentage of energy retained during charging | Impacts operational costs |
| Manufacturer | Representative Product | Chemistry Type |
|---|---|---|
| Panasonic | NCR18650B | Lithium-ion |
| BYD | Blade Battery | Lithium Iron Phosphate |
| Samsung SDI | INR18650-30Q | Nickel Cobalt Manganese (NCM) |
| Exide Technologies | Chloride SLA | Lead-Acid |
| LG Chem | LGDBHE21865 | Lithium-ion Polymer |
Key considerations:
Example: Select LiFePO4 for solar storage systems requiring 5000+ cycles and wide temperature tolerance.